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Oxotriruthenium acetate complex

Oxotriruthenium acetate complex [Tris(aquo)hexa-fi-acetato-ft3-oxotriru-thenium acetate], [Ru3 0(0C0CH3)5(H2 0)3]0C0CH3. Mol. wt. 585.06, green powder. Soluble in water, lower alcohols, and DMF. [Pg.425]

Preparation. This oxotriruthenium acetate complex is obtained by treating ruthenium trichloride hydrate with acetic acid and sodium acetate in ethanol (1 hr. reflux). It can be purified by crystallization from methanol—acetone. [Pg.425]

The oxotriruthenium cluster complex [Ru30 (OCOCH3) 6(H20) 3] [OCOCH3] which we had used as ruthenium(II) acetate (19), can be used as a catalyst, but small amounts of water are necessary for solubility, and long reaction times are required for reasonable conversions at mild conditions (Table I). [Pg.183]

See other pages where Oxotriruthenium acetate complex is mentioned: [Pg.427]    [Pg.427]    [Pg.3881]    [Pg.518]   
See also in sourсe #XX -- [ Pg.426 ]

See also in sourсe #XX -- [ Pg.426 ]



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