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Oxodiperoxymolybdenum hexamethylphosphoric triamide

Oxodiperoxymolybdenum(pyridine)(hexamethylphosphoric triamide) Molybdenum, (hexamethylphosphoric triamide)oxodiperoxy(pyridine)- (8,9) (23319-63-3)... [Pg.136]

HYDROXYLATION OF ENOLATES WITH OXODIPEROXYMOLYBDENUM(PYRIDINE)-(HEXAMETHYLPHOSPHORIC TRIAMIDE), MoOc-Py-HMPA (MoOPH) ... [Pg.227]

Arylsulfonyloxaziridines, 23 (Camphorylsulfonyl)oxaziridines, 64 Oxodiperoxymolybdenum(pyridine)-(hexamethylphosphoric triamide),... [Pg.359]

Oxodiperoxymolybdenum(pyridine)-(hexamethylphosphoric triamide), 21 Perbenzoic acid, 238 a to a carbonyl group 2-Arylsulfonyloxaziridines, 23 (Camphorylsulfonyl)oxaziridines, 64 m-Chloroperbenzoic acid, 76, 334 Oxodiperoxymolybdenum(pyridine)-(hexamethylphosphoric triamide), 227... [Pg.367]

Titanium(IV) isopropoxide, 311 a,(3-Epoxy aldehydes and ketones Fluorine-Acetonitrile, 135 Oxodiperoxymolybdenum-(pyridine)(hexamethylphosphoric triamide), 227 a,(3-Epoxy silanes Allyltriisopropylsilane, 11 m-Chloroperbenzoic acid, 76 Esters (see also Dicarbonyl compounds, Unsaturated esters)... [Pg.389]

Mercury(II) chloride, 175, 182 Mercury(II) trifluoroacetate, 175 Molybdenum Compounds Molybdenum carbonyl, 194 Molybdenum(VI) oxide, 279 Oxodiperoxymolybdenum(pyridine)-(hexamethylphosphoric triamide),... [Pg.410]

Enolate Hydroxylation. Treatment of the sodium enolates with the Davis oxaziridine reagent affords the hydroxylated products with the same sense of induction as the alkylation products (eq 23). Although high diastereoselectivity may be achieved with Oxodiperoxymolybdenum(pyridine)(hexamethylphosphoric triamide) (MoOPH), such reactions proceed in lower yields. [Pg.60]

Oxodiperoxymolybdenum-pyridine-hexamethylphosphoric triamide, MoOj CjHsN-HMPA (MoOPH), which is prepared from molybdenum trioxide, M0O3 [531,532], hydroxylates the enolates of ketones and esters in the a position with respect to the carbonyl groups [537, 532, 533] and, in the presence of mercuric acetate, converts acetylenes into a-dicarbonyl compounds [534]. [Pg.21]

Oxidation of ketones to a-hydroxyketones by means of oxodiperoxymolybdenum (pyridine) (hexamethylphosphoric triamide) (MoOPH) prepared and M0O3, 30% H2O2, HMPA and pyridine (see 1st edition). [Pg.391]

See other pages where Oxodiperoxymolybdenum hexamethylphosphoric triamide is mentioned: [Pg.245]    [Pg.127]    [Pg.365]    [Pg.386]    [Pg.310]    [Pg.5]    [Pg.249]   


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Hexamethylphosphoric

Hexamethylphosphoric triamide

Hexamethylphosphorous

Oxodiperoxymolybdenum

Oxodiperoxymolybdenum (hexamethylphosphoric

Triamide

Triamides

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