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Oxochromium -amine complexes

Recent Applications of Oxochromium-Amine Complexes as Oxidants in Organic Synthesis. A Review"... [Pg.241]

Oximes, formation by nitrosation, 7, 6 Oxochromium(VI)-amine complexes, 53, 1 Oxo process, 56, 1... [Pg.592]

The mechanism of picolinic acid (PA)-catalysed oxidation of formic acid by chro-mium(VI) involves the formation of a Cr(VI)-PA chelate complex in a pre-equilibrium step followed by attack at the Cr(VI) centre by the substrate, leading to a ternary complex within which electron transfer occurs giving a Cr(IV)-PA complex and CO2. The Cr(IV)-PA complex reacts faster with the substrate, ultimately giving rise to a Cr(III)-PA complex. The reaction is catalysed by anionic surfactants and inhibited by cationic surfactants. The oxidation of alcohols by modified oxochromium(VI)-amine reagents has been reviewed. ... [Pg.205]

See other pages where Oxochromium -amine complexes is mentioned: [Pg.885]    [Pg.885]    [Pg.885]   
See also in sourсe #XX -- [ Pg.53 ]



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