Oximes Vilsmeier-Haack reaction

Hydrazones are also useful substrates in the preparation of pyrazoles. Reaction of N-monosubstituted hydrazones with nitroolefins led to a regioselective synthesis of substituted pyrazoles <060L3505>. lf/-3-Ferrocenyl-l-phenylpyrazole-4-carboxaldehyde was achieved by condensation of acetylferrocene with phenylhydrazine followed by intramolecular cyclization of the hydrazone obtained under Vilsmeier-Haack conditions <06SL2581>. A one-pot synthesis of oxime derivatives of l-phenyl-3-arylpyrazole-4-carboxaldehydes has been accomplished by the Vilsmeier-Haack reaction of acetophenone phenylhydrazones <06SC3479>. 

Pyrrole, 2-acetyl-1 -(2-hydroxyethyl)-5-nitro-cydization, 4, 74 ipso substitution, 4, 243 Pyrrole, 2-acetyl-1-methyl-dipole moment, 4, 194 photocydization reactions with 2,3-dimethylbut-2-ene, 4, 269 Pyrrole, 3-acetyl-4-methyl-Vilsmeier-Haack formylation, 4, 222 Pyrrole, 2-acetyl-3-nitro-reduction, 4, 297 Pyrrole, acyl-basicity, 4, 207 isomerization, 4, 208 oximes... 

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