Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Oximes carbon-centred radicals

Cobalt(II)-bis((Z)-2-hydroxy-5,5-dimethyl-1 -(4-methylpiperazin-l -yl)hex-2-ene-1,4-dione) efficiently catalyses the aerobic oxidative 5-exo cyclization of )5,) -unsaturated oximes to give isoxazolines. Carbon-centred radicals are generated in the basic cyclization step. The predominant oxidative products of the reaction carried out in the presence of i-PrOH and TBHP are (16), whereas reductive products (17) are selectively obtained when the reaction is carried out in toluene in the presence of cyclohexa-1, 4-diene. " ... [Pg.109]


See other pages where Oximes carbon-centred radicals is mentioned: [Pg.156]    [Pg.83]    [Pg.276]    [Pg.452]   
See also in sourсe #XX -- [ Pg.765 ]

See also in sourсe #XX -- [ Pg.4 , Pg.765 ]

See also in sourсe #XX -- [ Pg.4 , Pg.765 ]




SEARCH



Carbon centres

Carbon radicals

Carbon-centred

Carbon-centred radicals

Carbonate radical

Centres radical

Oxime carbonates

Oximes carbon

© 2024 chempedia.info