Oximes, amino Heck reactions

The amino-Heck reaction, which proceeded through N—O bond cleavage of oxime derivatives, has been... [Pg.52]

An N-0 bond in oxime derivatives undergoes oxidative addition to form a Pd-imino bond. New Pd-catalyzed reaetions of oximes, such as the amino Heck reaction, have been discovered (see Chapter 3.2.10) [34]. [Pg.9]

Herrmann WA, Brossmer C, Reisinger CP, Riermaier T, Ofele K, Beller M (1997) Coordination chemistry and mechanisms of metal-catalyzed C-C coupling reactions. Part 10. Palladacycles efficient new catalysts for the Heck vinylation of aryl halides. Chem Eur J 3 1357-1364 Iyer S, Jayanthi A (2001) Acetylferrocenyloxime palladacycle-catalyzed Heck reactions. Tetrahedron Lett 42 7877-7878 Iyer S, Ramesh C (2000) Aryl-Pd covalently bonded palladacycles, novel amino and oxime catalysts di- x-chlorobis(benzaldehydeoxime-6-C,AT)dipalla-dium(II), di- x-chlorobis(dimethylbenzylamine-6-C,A)dipalladium(II) for the Heck reaction. Tetrahedron Lett 41 8981-8984 Jeffery T (1984) Palladium-catalysed vinylation of organic halides under solid-liquid phase transfer conditions. J Chem Soc Chem Commun 1287-1289 (b) idem,... [Pg.97]

Iyer, S. Ramesh, C. Aryl-Pd covalently bonded palladacycles, novel amino and oxime catalysts for the Heck reaction. Tetrahedron Lett. 2000, 41, 8981-8984. [Pg.308]

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