Oxides, thermal decomposition oxygen partial pressure

Thermal Decomposition of GIO2. Chloiine dioxide decomposition in the gas phase is chaiacteiized by a slow induction period followed by a rapid autocatalytic phase that may be explosive if the initial concentration is above a partial pressure of 10.1 kPa (76 mm Hg) (27). Mechanistic investigations indicate that the intermediates formed include the unstable chlorine oxide, CI2O2. The presence of water vapor tends to extend the duration of the induction period, presumably by reaction with this intermediate. When water vapor concentration and temperature are both high, the decomposition of chlorine dioxide can proceed smoothly rather than explosively. Apparently under these conditions, all decomposition takes place in the induction period, and water vapor inhibits the autocatalytic phase altogether. The products of chlorine dioxide decomposition in the gas phase include chlorine, oxygen, HCl, HCIO, and HCIO. The ratios of products formed during decomposition depend on the concentration of water vapor and temperature (27). 

Tests on tin oxide fiber coatings in model composite systems indicated some crack deflection at the coating-fiber interface (Siadati et al., 1991 Venkatesh and Chawla, 1992). However, tensile tests of tin oxide coated alumina fiber-reinforced alumina matrix composites demonstrated a decrease in the extent of fiber pullout as the density of the matrix phase was increased. This led to increasingly brittle fracture behavior in these composites (Goettler, 1993). Tin oxide also has thermal stability problems at elevated temperatures (Norkitis and Hellmann, 1991). For example, in the presence of air at temperatures above 1300°C (2,372°F), tin oxide (solid) decomposes into SnO (gas) and Oj (gas). This decomposition occurs at even lower temperatures when the partial pressure of oxygen in the test environment is reduced. 

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