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Oxidative Mn complexes

The Mn(IV)(salpn)Cl2 is a good oxidant, showing a reduction potential at +890 mV versus SCE. Other highly oxidized Mn complexes that contain chlorine have been shown to chlorinate alkanes, alkenes, and... [Pg.292]

Fig. 7. (A) The oxidation states of Mn in the various S-states. The model incorporates a histidine radical formation in the Sj-state with no oxidation of Mn in the Sj- Sa transition the model also accommodates the 1 0 1 2 proton-release pattern in the Kok cycle (B) a proposed topological model for the photosynthetic water-oxidizing Mn-complex based on XAS and EPR studies. Figure source (A) [adapted] and (B) Sauer, Yachandra, Britt and Klein (1992) The photosynthetic water oxidation complex studied by EPR and X-ray absorption spectroscopy. In VL Pecararo (ed) Manganese Redox Enzymes, pp 141-175. VCH Publ. Fig. 7. (A) The oxidation states of Mn in the various S-states. The model incorporates a histidine radical formation in the Sj-state with no oxidation of Mn in the Sj- Sa transition the model also accommodates the 1 0 1 2 proton-release pattern in the Kok cycle (B) a proposed topological model for the photosynthetic water-oxidizing Mn-complex based on XAS and EPR studies. Figure source (A) [adapted] and (B) Sauer, Yachandra, Britt and Klein (1992) The photosynthetic water oxidation complex studied by EPR and X-ray absorption spectroscopy. In VL Pecararo (ed) Manganese Redox Enzymes, pp 141-175. VCH Publ.
See other pages where Oxidative Mn complexes is mentioned: [Pg.346]    [Pg.101]    [Pg.323]   
See also in sourсe #XX -- [ Pg.86 ]



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