Oxidation cyclodecane

Bis-[aryl-hydrazono]-cyclodecaneiibergefuhrt. Durch Oxidationdieser Hydrazone mit Blei(IV)-acetat werden 9,10-Bis-[arylazo]-dekaline I sowie l,6-Bis-[arylazo]-l,6-diacetoxy-cyclodecane II in unterschiedlichen Ausbeuten gebildet. Zur Oxidation werden die Hydrazone bei 20° in Dichlormethan zwei Stunden mit Blei(IV)-acetat behandelt2 ... 

However, Baeyer-Villiger oxidation of trispiro[2.0.2,0.2.1]cyclodecan-7-one (7) gave the corresponding y-lactone 8 which did not undergo the expected thermal or photochemical decarboxylation. ... 

The first Gif-Orsay system (Pt-anode, Hg-cathode, cpe, TEABF4 in pyridine-acetic acid, divided cell) converted adamantane to 3.5% 1-adamantanol, 0.7% 2-adamantanol and 3.0% adamantone. Replacement of acetic acid by trifluoroacetic acid and its continuous addition to maintain a constant acidity improved the coulombic yield and selectivity. The oxidation of adamantane yielded 18% product with a C /C ratio of 8.5, this one of cyclodecane 21.1% product, and this one of trans-decalin 22.2% product, with a C /C ratio of 36. The results come close to those obtained in the chemical system. The third system... 

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