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Oxidation and Reduction of CO

Table 6. Half-wave potentials (V vs. SCE) for oxidation and reduction of Co(TPP)(R)... Table 6. Half-wave potentials (V vs. SCE) for oxidation and reduction of Co(TPP)(R)...
A few studies have appeared dealing with substitutions brought about by oxidation and reduction of co-ordinated ligands. Mention has already been made in this section of the reactions of co-ordinated azides, amides, and isocyanates with NO+. The reverse process (attack at co-ordinated NO+) is postulated to have a reactivity pattern which correlates with the i.r. N—O stretching frequencies. Co-ordinated NO+ behaves as an electrophile if the N—O stretching frequency is less than 1886 cm and the force constant is less than 13.8 mdyn A . A study of the rate of reaction of cis- and /ra -[Co(en)2(N02)2]+ ions with hydrazoic acid has also appeared ... [Pg.157]

See other pages where Oxidation and Reduction of CO is mentioned: [Pg.572]    [Pg.263]    [Pg.264]    [Pg.266]    [Pg.268]    [Pg.270]    [Pg.272]    [Pg.276]    [Pg.278]    [Pg.280]    [Pg.282]    [Pg.284]    [Pg.286]    [Pg.550]    [Pg.550]    [Pg.551]    [Pg.551]    [Pg.552]    [Pg.553]    [Pg.554]    [Pg.555]    [Pg.556]    [Pg.557]    [Pg.559]    [Pg.560]    [Pg.561]    [Pg.562]    [Pg.563]    [Pg.564]    [Pg.565]    [Pg.566]    [Pg.567]    [Pg.568]    [Pg.569]    [Pg.570]    [Pg.571]    [Pg.572]    [Pg.574]   


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CO oxidation

Co-reductant

Co-reduction

Oxidants and reductants

Oxidation and reduction

Reduction of CO

Reduction, of oxides

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