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Outer-Sphere Interactions, Association and Self-ionization of Solvents

Outer-Sphere Interactions, Association and Self-ionization of Solvents [Pg.221]

It has been mentioned in Section III that the polarographic reduction of metal cations occurs in water at much more negative potential [Pg.221]

Outer-sphere effects occur also when an anion is acting as the [Pg.222]

It has been mentioned in Section III that [CoCl4] is unstable in water even in the presence of large amounts of alkali metal chlorides. In contrast [CoCl4] is quantitatively formed in concentrated aqueous solutions of hydrochloric acid (66). Outer-sphere interactions between water molecules and hydronium ions will lead to the formation of highly aggregated clusters [H(H20) ]. In this way the concentration of free [Pg.223]

Chakge Distbibution for Hydrated Lithium aed Fluoride Ions (Single Hydration Shell) [Pg.225]


V. Outer-Sphere Interactions, Association and Self-ionization of Solvents. ... [Pg.189]




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Associated solvents

Associative ionization

Interacting spheres

Interactions) associative

Ionization solvent

Ionization sphere

Outer ionization

Outer sphere

Outer-sphere association

Self-association

Self-interaction

Self-ionization

Solvents association

Solvents ionizing

Solvents, interactive

Spheres interactions

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