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Osmium hydrido carbonyls

The unsaturated osmium hydrido carbonyl cluster ( i2-H)2Os3(CO)io reacts with a wide variety of Lewis bases, L,264 according to the following equation ... [Pg.58]

CioH20,oOs3Ci,H3, Osmium, p-carbonyl-noncarbonyl(T -cyclopentadienyl)-di- jL-hydrido-cobtilttri-, 25 195 C,oH30,Os3Ci4H5, Osmium, nonacarbonyI(Ti -cyclopentadienyl)-tri- jL-hydrido-cobalt-tri-, 25 197... [Pg.248]

PAuHO,oOs3C2bH,5, Osmium, deca-carbonyl-/i-hydrido[ n-(triphenylphosphine)gold]tri-,... [Pg.440]

C4 4H3 8CI2N2OOSP2, Hydrido(carbonyl)(phenyldiazo)bis(triphenylphos-phine)osmium(0) dichloromethane solvate, 41B, 1213 C44H39CI5N2P2RU, Trichloro(p-tolyldiazo)bis(triphenylphosphine)ruthenium dichloromethane solvate, 41B, 1197 C44H39N2NiP3, Dicyanotris-(5-ethyl-5H-dibenzophosphole)nickel(II),... [Pg.640]

Osmium(n).—Group VII Donors. Hydrido- and halogeno-carbonyl complexes. Carbonylation of [OsHX(CO)(PCy3)2] has produced the novel dicarbonyl hydride [OsHX(CO)2(PCy3)2] (X = Cl or Br Cy = tricyclohexyl).17 I.r. and n.m.r. data indicate the geometry (17). Addition of other ligands to the five-co-ordinate... [Pg.346]

General chemistry. The commonest oxidation states in the phosphines, arsines and stibines of osmium are II and III, but there are a number of osmium(IV) species and, with oxo, nitrido and hydrido ligands, osmium(VI) with carbonyls there are examples of osmium(0) and with nitrosyls (pp. 549-551) also of the 0 and — II states. Although the stereochemistry is octahedral in most cases... [Pg.569]

CIBF4lrN2P2Cj, Iridium (III), chloro-(dini-trogen)hydrido[tetrafluoroborate-(1 — )]bis(triphenylphosphine)-, 26 119 CIBFJrOP2Cj7H], Iridium(III), carbonyl-chlorohydrido[tetrafluoroborato(l - ))-bis(triphenylphosphine)-, 26 117 ClBFjIrOPjCaHj, Iridium(III), carbonyl-chloromethyl[tetrafluoroborato(l — )]-bis(triphenylphosphine)-, 26 118 CICH], Methane, chloro-, osmium complex, 27 205... [Pg.381]

N0s3C,3H3. Osmium, (acetonitrile)undc-cacarbonyltri-, 26 290, 28 232 OnNOsjCijHs, Osmium, undecacar-bonyl(pyridine)tri-, 26 291,28 234 0,NP20s3C4,H3, Osmate(l-), p-carbonyl-decacatbonyl-p-hydrido-tri-, p-nitrido-bis(triphenylphosphorusX 1+), 28 236 0,PRu3C,9H, Ruthenium, undecacar-bonyl(dimethylphenylphosphine)tri-, 26 273,28 223... [Pg.397]

OSH4P3Z1C34H43, Zirconium, bis(l,l(T )-cyclopentadienyl]tris(dimethylphenyl-phosphine-2KP)-tri- j-hydrido-hydrido-Ipfr-osmium-, 27 27 OSOP2SC42H34, Osmium, carbonyl(5-thioxo-1,3-pen tadiene-1,5-diyl-C, C yS)bis(triphenylphosphine)-, 26 188... [Pg.400]

See other pages where Osmium hydrido carbonyls is mentioned: [Pg.67]    [Pg.109]    [Pg.179]    [Pg.266]    [Pg.439]    [Pg.389]    [Pg.408]    [Pg.439]    [Pg.276]    [Pg.278]    [Pg.351]    [Pg.43]    [Pg.58]    [Pg.169]    [Pg.180]    [Pg.195]    [Pg.569]    [Pg.3364]    [Pg.398]    [Pg.205]    [Pg.167]    [Pg.3363]    [Pg.267]    [Pg.342]    [Pg.569]    [Pg.342]    [Pg.354]    [Pg.379]    [Pg.397]    [Pg.401]    [Pg.401]    [Pg.4023]    [Pg.398]   


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