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Osmium compounds decarbonylation

Chemical Properties. Compound 2 is readily decarbonylated upon exposure to UV irradiation.5 Irradiated solutions of 2 readily yield addition products of sulfur containing small molecules such as COS, CS2, and H2S. In the absence of reagents it will form the hexanuclear compound Os6(CO)17(/r4-S)2. It reacts with other metal complexes to form higher nuclearity osmium clusters and heteronuclear metal cluster compounds.5,11,12... [Pg.306]


See other pages where Osmium compounds decarbonylation is mentioned: [Pg.267]    [Pg.26]    [Pg.67]    [Pg.784]    [Pg.13]    [Pg.30]    [Pg.1068]    [Pg.212]    [Pg.390]    [Pg.453]    [Pg.29]   
See also in sourсe #XX -- [ Pg.354 ]




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