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Osmium complexes alkoxo

The formation of the first osmium hydrido(alkoxo) complex, a yellow air-stable and thermally stable hydrido(methoxo)osmium(II) complex, trans-[OsH(OMe)(Cl) (NO) (P Pr3)2] (72), by the oxidative addition of MeOH to a 16-electron complex, trans-[OsCl(NO)(P Pr3)2] (71) was briefly reported (Eq. 6.22) [51]. [Pg.186]

Osmium complexes, 519-619 alkaloids, 569 alkoxo, 596 amido, 557 amines, 557 bidentate, 530 monodentate. 530 amino acids, 602... [Pg.1297]

Similarly, reference is made to another more recent review (41) of the author s contributions to the chemistry of rhodium, iridium, rhenium, osmium and ruthenium alkoxo, and hydroxo complexes, following a similar earlier publication (40) on the alkoxo derivatives of platinum metals. Reference may also be made to the first X-ray structural study (265, 266) of a siloxy derivative, [(cod)Rh(/i-OSiMe)3]2. [Pg.327]

See other pages where Osmium complexes alkoxo is mentioned: [Pg.183]    [Pg.378]    [Pg.321]    [Pg.524]   
See also in sourсe #XX -- [ Pg.596 ]

See also in sourсe #XX -- [ Pg.4 , Pg.596 ]



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