Organosulfur molecules and radicals

Ultraviolet Photodissociation Studies of Organosulfur Molecules and Radicals Energetics, Structure Identification, and Internal State Distribution (Cheuk-Yiu Ng). 

PHOTODISSOCIATION STUDIES OF ORGANOSULFUR MOLECULES AND RADICALS ENERGETICS, STRUCTURE IDENTIFICATION,... 

We have used the laser resonance-enhanced multiphoton ionization (REMPI) method to probe the final state distributions of S atoms formed in the 193-nm photodissociation of several organosulfur molecules and radicals [58-60], Using the rate-equation scheme and calibrating with the known photodissociation cross sections for the formation of S( P2,i,o, >2) in the 193-nm photodissociation of CS2, we have estimated the absolute cross sections for the photodissociation of organosulfur radicals HS [59,60] and CH3S [58,60] leading to the formation of S( P2,i,o o)-... 

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