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Weak single bonds organometallics

The vanadium—vanadium bond length in the organometallic complex ( 5-C5H5)2V2(C4H8)2 (Figure 9) of 2.315(1) A is somewhat controversial.31 32 Similar to /i-( 5 5-cyclooctatetraene)bis[( p-cyclopentadienyl)divanadium]33,34 with a metal-metal distance of 2.439(1) A, the interpretation of the interaction between the two vanadium centers has been proposed to be a triple bond, a very short single bond,33 or a weak double bond.35... [Pg.581]


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See also in sourсe #XX -- [ Pg.225 ]




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