Organometallics heterocumulenes

Bardaji, M., Gimeno, M.C., Jones, P.G., Laguna, A., Laguna, M., Merchan, F. and Romeo, I. (1997) Carbon-Carbon Coupling via Nucleophilic Addition of a Gold(l) Methanide Complex to Heterocumulenes. Organometallics, 16(5), 1083-1085. 

The Chemistry of Cumulenes and Heterocumulenes The Chemistry of Organometallic Compounds The Chemistry of Sulphur-containing Compounds Supplement C The Chemistry of Triple-bonded Functional Groups Supplement D The Chemistry of Halides and Pseudo-halides Supplement E The Chemistry of —NH, —OH, and —SH Groups and their Derivatives... 

A143. H. Ulrich, Cycloaddition Reactions of Heterocumulenes. Academic Press, New York, 1967. 364 pp. Thirty pages deal with organometallic compounds. 

Heterocumulenes such as R1N=C=0, RAN—C=S and R1N=S=0 react smoothly with polar organometallic intermediates [50]. Although in many procedures the counter ion is Li , other alkali metal ions or MgX might also... 

Yasuda H, Okamoto T, Matsuoka Y, Nakamura A, Kai Y, Kanehisa N, Kasai N (1989) Diverse reaction courses in the controlled carbometalation of heterocumulenes with zirconium-diene complexes and molecular structures of carbon dioxide, isocyanate and ketene 1 1 and 1 2 inserted compounds. Organometallics 8 1139-1152... 

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