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Organometallic gold -alkynyl

Copper(I) (See Copper Organometallic Chemistry), Silver(I) (See Silver Organometallic Chemistry) and Gold(I) (See Gold Organometallic Chemistry) Alkynyls... [Pg.5429]

Bardaji, M., Lagrma, A. and Jones, P.G. (2001) Reactivity of anAcetylenephosphine Gold(III) Precursor Addition to the Triple Bond or Formation of Alkynyl Derivatives. Organometallics, 20(18), 3906-3912. [Pg.175]

Organometallic alkynyl complexes exhibit a rich coordination chemistry with copper(l), silver(I), and gold(I) irms, and the ability of alkynyl groups to coordinate to metal centers in a- and Jt-bonding modes has made them versatile ligands in the... [Pg.186]

Gold(l) alkynyl derivatives containing the water-soluble PTA and DAPTA phos-phane ligands (see examples 34-36 in Figure 4.10) are cytotoxic in cancer cells and their cellular uptake was confirmed by fluorescence microscopy using the luminescent properties of these organometallics [117]. As expected, the complexes lack... [Pg.155]

Gd-Rubio J, Camara V, Bautista D, Vicente J. Dinuclear alkynyl gold(I) complexes containing bridging N-heterocycHc dicarbene ligands new synthetic routes and luminescence. Organometallics. 2012 31 5414-5426. [Pg.286]


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Gold-alkynyl

Organometallic gold -alkynyl complexes

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