Organometallic compounds cyanation

Cyanation of vinylic organometallic compounds Addition to activated alkynes (Michael)... 

Unsaturated Nitriles, Nitro Compounds, and Sulfonic Acids and Esters 2-33 Cyanation of vinylic organometallic compounds... 

Side Note 17.8. Diazene anions have a key role in both the Wolff-Kishner reduction and its alternative, the Reductive Cyanation semicarbazone reduction (Formula D in Figure 17.67 and Formula G in Figure 17.68, respectively) they decompose into elemental nitrogen and an organometallic compound. The italics immediately explain what happens in the second step of the reductive cyanation of a ketone shown in Figure 17.69. 

Many other modifications to acrylic adhesives are useful. Improved heat resistance of acrylic adhesives can be achieved by incorporating small amounts of epoxy resin into the formulations,77 or by including cyanate esters and organometallic compounds to provide an additional crosslinking mechanism.78 Lower sensitivity of oxygen can be achieved by... 

The various classes of compounds featuring carbon-nitrogen multiple bonds that are substrates for organometallic addition comprise azomethines, immonium ions, nitrones, hydrazones, oxime ethers, amidinesimidoyl halides, nitriles, isonitriles, and cyanates. Dicyclohexylcarbodiimide is omitted here because it has been included in the carbonyl section (p.l 16) side by side with isocyanates and isothiocycanates. 

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