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Organomercury compounds vinyl substitutions

It was demonstrated by Heck in the late 1960s that arylpaUadium salts, prepared by trans-metallation of organomercury compounds, constitute useful reactants in various vinylic substitution reactions.f t Independently, Moritani, Fujiwara, and colleagues conducted similar vinylic substitutions, but generated the organopalladium intermediates by direct electrophilic palladation of arenes.t ° In these reactions the palladium(II) salt employed is reduced to paUadium(O) (Scheme ). ... [Pg.1133]

See other pages where Organomercury compounds vinyl substitutions is mentioned: [Pg.838]    [Pg.839]    [Pg.75]    [Pg.482]    [Pg.75]    [Pg.481]    [Pg.240]   


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Organomercurial compounds

Organomercurials

Organomercury

Organomercury compounds

Organomercurys

Substituted Compounds

Substitution compounds

Substitution, vinyl

Vinyl compounds

Vinylic compounds

Vinylic substitution

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