Organomagnesium structures

The investigation of organomagnesium structures is an active area of research there is a steady stream of papers dedicated to this subject. After... 

The majority of organomagnesium structures is monomeric with magnesium in a distorted tetrahedral ensironment of four lioands as shown in... 

The stability of synthesized organomagnesium structures depends on atomic metal content Xat— that is, Nm/Nm + Np, where Nm and N are the amount of metal atoms and polymer chain units, respectively. At high Xat of Mg (>40... 

Under the conditions used for the reductive cleavage of the O—N bond in isoxazoles, a similar reaction readily occurs with isoxa-zolines, e.g. on treatment with organomagnesium compounds and on catalytic hydrogenation.- Hydrogenolysis of the O—N bond (180 181 182 183) was used to elucidate the structure of isoxa-zolones from -ketoesters. -... 

Intramolecular coordination in organomagnesium compounds is a common feature of their structures, and the subject has been reviewed.161 The diorganomagnesium adducts, MgR2(L) (R = methyl, ethyl L = tmeda, pmdta),... 

On reaction with MeMgCl, the lithium triazine Li(TF[F)2 N[C(Ph)=N]2 CBut(Bun) yields the methylmagnesio-dihydrotriazine 86 (Equation (18)). An X-ray crystal structure determination revealed that the compound closely resembled its lithio precursor the formal substitution of MeMg+ (Mg-C = 2.164(3) A) for Li+ did not produce the substantial structural differences often observed between isoleptic organolithium and organomagnesium systems.267... 

Organolithium compounds, 2 69 ring stacking, 37 82-92 systems capable of, 37 82-83 uncomplexed, structure, 37 53-54 X-ray crystal structure, 37 48 Organomagnesium halides, 2 71 Organomercury compounds, see Mercury, -carbon compounds Organometallic complexes... 

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