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Organoleads hydrogen halides

The reaction of hexaorganodileads with hydrogen halides has been observed to take place readily at room temperature (295,296,311-313,339, 351), The acid cleavage reactions are more complex since organolead hydrides are apparently not formed. From the products isolated the following series of reactions has been suggested (308,339) ... [Pg.74]

The usual method for the preparation of organolead halides is by the action of hydrogen halides upon tetra-organoleads. Initial reaction involves fission of one carbon-lead bond, with loss of a further alkyl/aryl group under more vigorous conditions. [Pg.138]

Because of the lower metal-carbon and metal-hydrogen bond strength, organolead hydrides are particularly unstable species and represent the least stable of those of the group 14 elements. Triorganolead hydrides are obtained at low temperatures by reduction of the halides with LiAlH4 (equation 45), but they decompose at 0 °C. [Pg.552]

Table 10 contains examples of some representative organolead halides. The fluorides are best prepared by the action of alkali fluorides upon organolead halides, or hydrogen fluoride upon alkyl-lead hydroxides. ... [Pg.139]

See other pages where Organoleads hydrogen halides is mentioned: [Pg.46]    [Pg.86]    [Pg.68]    [Pg.48]    [Pg.68]    [Pg.248]    [Pg.278]    [Pg.170]   
See also in sourсe #XX -- [ Pg.2 , Pg.3 , Pg.4 , Pg.5 , Pg.6 , Pg.7 , Pg.14 ]



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