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Organogold compounds oxidative addition

Figure 4.25 Synthesis of an organogold(III) compound by an unusual oxidative addition... Figure 4.25 Synthesis of an organogold(III) compound by an unusual oxidative addition...
Figure 4.33 Syntheses of organogold compounds by oxidative addition to a gold(l) compound. Figure 4.33 Syntheses of organogold compounds by oxidative addition to a gold(l) compound.
The cychc gold(I) phosphonium methylide heterocycles are the precursors for the few organogold(II) species reported. Oxidative addition (see Oxidative Addition) of halogen and alkyl halides leads to bicyclic compounds containing a transaimular Au Au bond (equations 28 and 29). These reactions are surprisingly facile and are now known to be... [Pg.1466]


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