Organogermanium Phosphides

Organogermanium phosphorous derivatives include phosphines, phosphine imines, tris(trimethylgermyl)phosphine complexes with transition metals and mixed organosilicon and organotin phosphides. The compounds listed in Table 71 are prepared by methods from the following scheme. [Pg.223]

By rxn. of M GeNMe2 with in Et20 in inert atm., in 607o yield [Pg.223]

with Cr(CO)e under UV irradiation (Me3Ge)3PCr(C0)5 + CO (I852). Fe(CO)s under UV irradiation (Me3Ge)3PFe(C0)4 + CO (27 8). [Pg.223]

Other organogermanivim phosphides are listed in Table 7I and in Chapter 6.5.1. [Pg.224]

By rxn. of Me3GeCl with NaaAs in liq. NI under exclusion of air [Pg.224]

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