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Organocobalt complexes catalytic hydrogenation

This paper evaluates the role of the hydrido complex in various carbon-carbon double bond hydrogenations and carbon-halogen bond hydrogenolyses, and the relationship between the two reaction types. Evidence for free radicals, as well as organocobalt complexes ( metal-complexed radicals), as intermediates will be presented. The relationship of organocobalt complex stability to catalytic hydrogenation will also be discussed. [Pg.208]

A reassessment of the experimental data concerning the catalytic hydrogenation of polyaromatic hydrocarbons by cobalt carbonyl under oxo conditions has resulted in the postulate that the reaction involves free radicals rather than organocobalt complexes. ... [Pg.364]

See other pages where Organocobalt complexes catalytic hydrogenation is mentioned: [Pg.395]    [Pg.433]    [Pg.207]    [Pg.229]    [Pg.229]    [Pg.230]    [Pg.230]    [Pg.378]    [Pg.332]   
See also in sourсe #XX -- [ Pg.435 ]



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