Organic zeolite analogues

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Organic Zeolite Analogues as Enzyme Mimics in Water... 

Organic zeolite analogues are commonly referred to as porous solids. These materials promise a new range of applications, e.g., in pharmaceutical manufacture and in molecular sieves, sensors, and devices. They are crystalline or amorphous materials that permit the reversible passage of molecules through holes on their surface. Porous solids are classified according to pore diameter nanoporous or microporous (< 15 A), mesoporous (15—500 A) and macroporous (>500 A). The natural and synthetic inorganic zeolites with uniform pore sizes of 10-20 A are the classical examples of microporous materials with widespread use in industry. 

Aoyama, Y. Functional organic zeolite analogues. Top. Curr. Chem. 1998, 198, 132-161. 

Sawaki. T. Aoyama. Y.J. Immobilization of a soluble metal complex in an organic network. Remarkable catalytic performance of a porous dialkoxyzirconium polyphenoxide as a functional organic zeolite analogue. J. Am. Chern. Soc. 1999. 2L 4793-4798. 

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