Organic intervalence radicals

Although mueh of the researeh of our laboratory involves eleetron transfer in inorganie eoordination compounds, the applications of the SEC eell are not limited to studies of inorganie eompounds. Nelsen et diseovered an or-ganie radieal eomplex that was thought to be comparable to a traditional intervalenee complex in whieh a bridging-oxo played the role of the 

The (+1) peaks in this case are best approximated by a simple Gaussian/ Lorentzian overlap of two bands present in solution, and not the Bloch-type analysis appropriately used for rapidly exchanging systems. It is concluded that this particular organic mixed-valence complex is localised on the infrared timescale. 

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Electron transfer, in thermal and photochemical activation of electron donor-acceptor complexes in organic and organometallic reactions, 29, 185 Electron transfer, long range and orbital interactions, 38, 1 Electron transfer reactions within s- and p-bridged nitrogen-centered intervalence radical ions, 41, 185... 

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