Organic electrophiles organoboron

Suzuki, A. Recent advances in the cross-coupling reactions of organoboron derivatives with organic electrophiles. J. Organomet. 

A. R. Martin, Y. Yang, Palladium Catalyzed Cross-Coupling Reactions of Organoboronic Acids with Organic Electrophiles "Acta Chem. Scand. 1993, 47, 221-230. 

Grignard reagents are least tolerant of common organic electrophilic functional groups, such as carbonyl and nitro groups, while organoboron compounds tolerate most such electrophiles. 

Martin, A. R., Yang, Y. Paiiadium-catalyzed cross-coupling reactions of organoboronic acids with organic electrophiles. Acta Chem. Scand. 1993,47, 221-230. 

The cross-coupling reaction of 1 with palladium catalyst provides a convenient method for the synthesis of organoboronic esters from organic electrophiles (Scheme... 

As alternatives to the use of organic electrophiles, hypervalent iodonium com-ponndsf" and organolead compounds have been employed in cross-coupling with organoboron componnds. 

State-of-the-Art in Metal-Catalyzed Cross-Coupling Reactions of Organoboron Compounds with Organic Electrophiles... 

The cross-coupling of organoboron reagents with organic electrophiles in the presence of a base and a Pd catalyst is commonly referred to as the Suzuki-Miyaura reaction and has proved to be one of the most popular cross-coupling methodologies... 

The combination of rhodium catalysts and organoboronic acids has emerged recently as a powerful and ideal catalytic system in carbon-bond forming reactions. This tremendous system overcomes the functional group protection issue, but can also apply to catalytic asymmetric synthesis, which can provide much chiral product using a small amount of a chiral catalyst. This chapter reviews the development and scope of the rhodium-catalyzed addition of boronic acids to organic electrophiles [1]. 

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