Organic catalysts hydrohalogenation

Optical rotation, enantiomers, 281 Organic catalysts, 323, 347 crystal morphology, 348 hydrohalogenation, 347 Michael reactions, 350 photochemistry, 348 solid-state reactions, 349 see also specific reactions Organic halides, Grignard reagents, 187, 354 Organocopper chemistry, 199, 208, 292,... 

ChLorofluorocarbene generated by the thermal decomposition of dichlorofluoro-methylphenylmercury reacts with 2,3-dimethylindole to give 3-fluoro-2,4-di-methylquinoline, 3-chloro-2,4-dimethylqumoline and 3-(chlorofluoromethyl)-2,3-dimethylindole [f] (equation 1). Similar results are obtained when the chloro-fluorocarbene is generated from dichlorofluoromethane by base-catalyzed de-hydrohalogenation using a phase-transfer catalyst in an aqueous-organic solvent system [21 (equation 1). 

Marques, C. A., Selva, M. Tundo, P. (1994). Facile hydrodehalogenation with H2 and Pd/C catalyst under multiphase conditions 2. Selectivity and kinetics. Journal of Organic Chemistry, 59,14, 3830-3837, ISSN 0022-3263 Marques, C. A., Selva, M. Tundo, P. (1995). Facile hydrohalogenation with H2 and Pd/C catalyst under multiphase conditions 3. Selective removal of halogen from functionalized aryl ketones. 4. Aryl halide-promoted reduction of benzyl alcohols to alkanes. Journal of Organic Chemistry, 60, 8, 2430-2435, ISSN 0022-3263... 

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