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Oligothiophenes oxidation potentials

Table 6.1 Optical absorption bands, emission bands, oxidation potentials and electrical conductivities of a-oligoselenophenes anda-oligothiophenes... Table 6.1 Optical absorption bands, emission bands, oxidation potentials and electrical conductivities of a-oligoselenophenes anda-oligothiophenes...
Figure 9.8 Correlation of the first Pj and second (Bj oxidation potentials of oligothiophenes EC1T-EC6T vs the inverse of the chain length. Erom P. Bauerle, Adv. Mater. 4, 102 (1992), Copyright Wiley-VCH Verlag GmbH Co. KGaA. Reproduced with permission... Figure 9.8 Correlation of the first Pj and second (Bj oxidation potentials of oligothiophenes EC1T-EC6T vs the inverse of the chain length. Erom P. Bauerle, Adv. Mater. 4, 102 (1992), Copyright Wiley-VCH Verlag GmbH Co. KGaA. Reproduced with permission...
Hexyl end-capped hybrid oligothiophenes based on various combinations of thiophene and EDOT have been reported by Roncali and co-workers [118]. A synthetic route to oligomers alternating EDOT and thiophene up to the heptamer 48 was developed (Scheme 9.27). Electrochemical studies and theoretical calculations show that the positions of the EDOT units within the conjugated chain control the potential difference AEp between the first and second oxidation processes. [Pg.442]

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See also in sourсe #XX -- [ Pg.94 ]



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