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Oligosaccharides oxidation procedures

Oxidation of carbohydrates is probably the most efficient heterogeneously-catalyzed process since very high yield and selectivity are reported for reactions over solid catalysts. Despite important recent advances, the conversion of carbohydrates to HMF still requires further investigations. For reactions, in water, the yield of HMF is still too low due to the significant formation of side products. Today, several procedures for the conversion of monosaccharides, disaccharides, oligosaccharides, and starch in water into high value added materials are available. With cellulose, its heterogeneously-catalyzed conversion into useful products... [Pg.88]

Oxidation of 2-acetamido-2-deoxy-D-glucose derivatives with hypoiodite at 0° proceeds quantitatively, without side reactions, and is satisfactory as a procedure for end-group assay in oligosaccharides containing amino sugar residues.177 The possibility that (1 —> 3)-linked disaccharides may be degraded under the reaction conditions must not be overlooked. [Pg.259]


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Oligosaccharides oxidation

Oxidation procedure

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