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Oligosaccharides orthogonal strategy

The combination of two chemically distinct glycosylation reactions, in which one of the leaving groups is activated while the other one remains intact, and vice versa, has led to the discovery of the orthogonal strategy for oligosaccharide synthesis.4... [Pg.188]

Scheme 7.1 Oligosaccharide assembly traditional concept (left) and by an orthogonal strategy (right). Scheme 7.1 Oligosaccharide assembly traditional concept (left) and by an orthogonal strategy (right).
Notes and discussion. Trichloroacetimidates are versatile glycosyl donors and have played crucial roles in oligosaccharide assembly strategies [37, 38]. Takahashi et al. were the first to apply this strategy to a one-pot, two-step orthogonal glycosidation protocol [11]. [Pg.232]

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See also in sourсe #XX -- [ Pg.407 ]



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Orthogonal Strategy in Oligosaccharide Synthesis

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