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Olefin Dimerization and Oligomerization

In addition to a-additions to isocyanides, copper oxide-cyclohexyl isocyanide mixtures are catalysts for other reactions including olefin dimerization and oligomerization 121, 125, 126). They also catalyze pyrroline and oxazoline formation from isocyanides with a protonic a-hydrogen (e.g., PhCH2NC or EtOCOCHjNC) and olefins or ketones 130), and the formation of cyclopropanes from olefins and substituted chloromethanes 131). The same catalyst systems also catalyze Michael addition reactions 119a). [Pg.49]

For a review of olefin dimerization and oligomerization with all catalysts, see Fel dblyum Obeshchalova Russ. Chem. Rev. 1968,37, 789-797. [Pg.793]

Olefin additions to bridging alkylidenes yield dimetallacyclopentanes . These reactions also provide a mechanism for olefin metathesis, a topic not discussed here. Although addition of an olefin to a metal carbone, a 2n + In addition, would be symmetry forbidden in organic chemistry, ab initio calculations " of the conversion of a metal carbene-alkene to a metallocyclobutane show it to be a barrierless reaction. Metal d orbitals relax the symmetry restrictions for the In + 2n addition. The mechanism of reaction (p) has not been widely considered for the olefin polymerization, but it may be relevant to olefin dimerization and oligomerization—reaction (s), for example ... [Pg.659]


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Olefins oligomerization

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