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Of six-membered rings

The conformational features of six membered rings are fundamental to organic chemistry so it is essential that you have a clear understanding of the directional prop erties of axial and equatorial bonds and be able to represent them accurately Figure 3 17 offers some guidance on the drawing of chair cyclohexane rings... [Pg.117]

The backbone here is made up of six-membered rings in which the two rings share a common atom. These are called spiro polymers. [Pg.336]

Isoprene is highly reactive both as a diene and through its allyhc hydrogens, and its reactions are similar to those of butadiene (qv) (8). Apart from polymerisation, the most widely investigated isoprene reactions are the formation of six-membered rings by the Diels-Alder reaction ... [Pg.463]

The stmcture of kernite consists of parallel infinite chains of the Bion (6) composed of six membered rings (80). The polymeric nature of the anion is consistent with the slow rate of dissolution and crystallisation observed for kernite. [Pg.199]

The separate stems for three-, four- and five-membered rings containing nitrogen are used for historical reasons. Those for the different groups of six-membered rings are... [Pg.11]

Following a standard notation[ 12,13], a cylindrical tubule can be described by the (L,M) couple of integers, as represented in Fig. 1. When the plane graphene sheet (Fig. 1) is rolled into a cylinder so that the equivalent points 0 and M of the graphene sheet are superimposed, a tubule labeled (L,M) is formed. L and M are the numbers of six membered rings separating 0 from L and L from M, respectively. Without loss of generality, it can be assumed that L>M. [Pg.87]

For the sake of clarity, ten coordination sites are drawn a little further away from the surface of the particle in Fig. 15(a)-(c). These sites are real surface sites and the formal link is shown by a solid line. In this way the different C2 units are easily distinguished in the figure and the formation of six-membered rings is obvious. The planar tubule representations of Fig. 15(a )-(c ) are equivalent to those in Fig. 15(a)-(c), respectively. The former figures allow a better understanding of tubule growth. Arriving C, units are first coordinated to the catalyst coordination... [Pg.97]

Highly fluonnated alkanes are also reduced by alkali metals Lithium amalgam converts polytetrafluoroethyleneto acarbon polymer composed of monolayer nbbons of six membered rings with hthium atoms bound to the edges [i]... [Pg.297]

Dipolar cycloaddUions. Interest in 1,3-dipolar cycloadditions increased dramatically during the past 20 years, largely because of the pioneering studies of Huisgen [7, 2] The versatility of this class of pericychc reactions in the synthesis of five-membered-ring heterocyclic compounds is comparable with that of the Diels-Alder reaction in the synthesis of six-membered-ring carbocyclic systems (equation 1)... [Pg.797]

Reaction type 3 (equation 10), where the complete hetero-l,3-diene skeleton is incorporated into the newly formed ring system, occurs with compounds having both a nucleophilic center and an electrophilic center If these two functionalities are in positions 1 and 2, various types of six-membered ring systems become accessible 4,4-Bis(trifluoromethyl)-I,3-diaza-1,3-butadienes require only room temperature to react with acetyl cyanide to yield l,4,5,6-tetrahydropynmidin-6-ones [96] Likewise, certain open-chain 1,3-diketones (acetylacetone and acetoacetates) and the heterodiene form six-membered nng systems [97] (equation 19)... [Pg.848]

Reactions of vinylogous amides with methanesulfonyl chloride also led to the formation of six-membered rings. Here the initial attack on oxygen produces a zwitterionic intermediate which can collapse to an enol sulfonic acid lactone (383,469). [Pg.405]

The chemical reduction of enamines by hydride again depends upon the prior generation of an imonium salt (111,225). Thus an equivalent of acid, such as perchloric acid, must be added to the enamine in reductions with lithium aluminum hydride. Studies of the steric course (537) of lithium aluminum hydride reductions of imonium salts indicate less stereoselectivity in comparison with the analogous carbonyl compounds, where an equatorial alcohol usually predominates in the reduction products of six-membered ring ketones. [Pg.428]

The volume ends with a chapter by B. Stanovnik and M. Tisler of the University of Ljubljana, Slovenia, and A. R. Katritzky and O. V. Denisko of the University of Plorida on the annular tautomerism of six-membered ring heterocycles. This represents a further installment in our comprehensive update of heteroaromatic tautomerism, which was the subject of several chapters in Volumes 79 and 80 of this series. [Pg.307]

The Diels-Alder reaction is the most important method for the construction of six-membered rings. For example it can be used as a step in a benzo-anellation procedure. The experimental procedure is simple, and yields are generally good side reactions play only a minor role. [Pg.95]

An important application of the Friedel-Crafts acylation is the intramolecular reaction, leading to ring closure. This variant is especially useful for the closure of six-membered rings, but five-membered ring products and larger rings, as well as heterocycles, are also accessible ... [Pg.118]


See other pages where Of six-membered rings is mentioned: [Pg.288]    [Pg.1]    [Pg.2]    [Pg.3]    [Pg.4]    [Pg.5]    [Pg.6]    [Pg.7]    [Pg.8]    [Pg.9]    [Pg.10]    [Pg.11]    [Pg.12]    [Pg.13]    [Pg.14]    [Pg.15]    [Pg.16]    [Pg.17]    [Pg.18]    [Pg.19]    [Pg.20]    [Pg.21]    [Pg.22]    [Pg.23]    [Pg.26]    [Pg.27]    [Pg.136]    [Pg.691]    [Pg.155]    [Pg.870]    [Pg.214]    [Pg.348]    [Pg.49]    [Pg.254]    [Pg.108]   
See also in sourсe #XX -- [ Pg.28 ]




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A Symmetrical Example Conformations of Six-Membered Rings

Analysis of Six-membered Rings (Kellie and Riddell)

Aromatization of six-membered rings

Asymmetric Hydrogenation of Six-Membered Ring Heteroarenes

Chair-Boat Interconversion of Six-Membered Rings in the Solid

Conformations of the Six-Membered Rings

Enantioselective Organocatalyzed Synthesis of Six-Membered Rings

Formation of Six-Membered (and Larger) Rings

Formation of six-membered rings - Diels-Alder reactions

Non-Chair Conformations of Six-Membered Rings (Kellie and Riddell)

Of pyrazoles condensed to heteroaromatic five- and six-membered rings

Other Syntheses of Six-membered Rings

Reactions Leading to the Formation of Six-Membered Rings

Reactivity of Six-membered Rings

Ring Systems of more than Six Members Containing

Rings of More Than Six Members

Rings six-member

Structure of Six-membered Rings

Synthesis of Six-Membered Rings (Diels-Alder Reaction)

Synthesis of six-membered ring

Transformation of a Six-membered Ring

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