Of anionic activated polymerization

Figure 2.7. Influence of different catalytic systems on the rate of anionic activated polymerization ofs-caprola-ctam in an adiabatic regime. Numbers on the curves correspond to numbers in the list in Table 2.1.

The polymerization kinetics of m-dodecalactam in chemical processing has been investigated in a more limited number of publications in comparison with e-caprolactam. It is not really possible to compare different data therefore only the results of Ref.37 will be discussed below. It was shown that up to a degree of conversionp 0.7, the kinetics of anionic activated polymerization of co-dode-calactam is described by the first-order equation ... 

In addition to these equations, it is necessary to introduce Eq.(2.22) for the kinetics of anionic activated polymerization of e-caprolactam and Eq. (2.52) for the kinetics of crystallization. Let us write the boundary and initial conditions at r = R... 

S.P., and Malkin, A.Y. (1973) On some features of the process of anionic activated polymerization of E-caprolactans under conditions of wave propagation. 

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