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Octanuclear iron cages

The oldest octanuclear Fe(III) cage is also the iron cage with the most heavily studied magnetic properties. [Fe8(0)2(0H)i2(tacn)6] (58) (tacn = 1,4,7-triazacyclononane), shown in Fig. 23, was first reported... [Pg.52]

The second octanuclear mixed chalcogen/carbonyl compound so far known is the complex anion [Fe8Te8(Te2)(CO)2o] . " " This novel cage system (Fig. 31) contains two cuboidal Fe4Te4(CO)ioTe2 fragments, which share the atoms of the ditelluride group. With a total of 144 valence electrons, the complex anion is electron-precise without any iron-iron bonds. [Pg.282]

See other pages where Octanuclear iron cages is mentioned: [Pg.206]    [Pg.206]    [Pg.53]    [Pg.146]    [Pg.148]    [Pg.21]    [Pg.50]    [Pg.51]    [Pg.54]    [Pg.54]    [Pg.54]    [Pg.100]    [Pg.146]    [Pg.168]   


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Octanuclear

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