Octamethylpyrophosphoramide oxidation

Octamethylpyrophosphoramide is also enzymicahy oxidized in vivo, as well as chemically by permanganate, to a highly effective anti-esterase.5... 

Octamethylpyrophosphoramide (ompa) has been shown to loosen ion pairs in solution178 and a 1 3 complex has been isolated with Mg(C104)2. The crystal structure shows that the ligand is bidentate and chelates to the cation through the phosphine oxide oxygens.179... 

Studies of the complex chemistry of the tervalent lanthanides show that coordination numbers higher than six are common, for example in the tetrakistropolonates 79), the complexes of the perchlorates with N,N-dimethylacetamide (DMA) (77) or octamethylpyrophosphoramide 61), of the iodides with N,IV-dimethylformamide (DMF) (76), the nitrates with triphenylphosphine (or arsine) oxide 46), and the -diketone... 

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