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Octakis phthalocyanine complexes

Recently, Swager has compared the mesomorphic properties of an octakis(tetra-decyloxymethyl)-phthalocyanine coppeifll) complex, Crys 80-Colhd 280-I, with the analogous octakis(tetradecyloxymethyl)tetra-2,3-thiophenoporphyiazine, Crys 49-Colhd 258-I [134]. X-ray difiiaction studies show that the lattice constants are 33.5 A for the phthalocyanine complex and 32.9 A for the thiophenoporphyr-... [Pg.332]

Di(trifluoroethoxy)phthalodinitrile 122 can be prepared from 2,3-dicyanohydroquinone 121 by alkylation with trifluoroethyltosylate in DMF [70], The 4,5-substituted dinitrile 125 is available from the 4,5-dibromocatechol 123 by consecutive alkylation with tosylate (DMF, K2CO3) and cyanation (CuCN, DMF) [70], 0=Ti" complexes of a- and p-octakis(trifluoroethoxy)phthalocyanines were prepared using these dinitriles 122 and 125 [70]. The Zn" complex of p-octasubstituted phthalocyanine was also reported [78],... [Pg.655]

Gurek AG, Basova T, Euneau D, Lebrun C, Kol tsov E, Hassan AK et al (2006) Synthesis, structure, and spectroscopic and magnetic properties of mesomorphic octakis(hexylthio)-substituted phthalocyanine rare-earth metal sandwich complexes. Inorg Chem 45(4) 1667-1676... [Pg.199]


See other pages where Octakis phthalocyanine complexes is mentioned: [Pg.379]    [Pg.84]    [Pg.155]    [Pg.17]    [Pg.314]    [Pg.335]    [Pg.98]    [Pg.100]    [Pg.106]    [Pg.381]    [Pg.97]    [Pg.67]    [Pg.1751]   
See also in sourсe #XX -- [ Pg.98 , Pg.99 ]




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