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Octahedral geometry xanthate structures

A] bond distances. The restricted bite distances of the xanthate ligands [the S—M—S chelate angles are 73.50(6) and 69.77(4)°, respectively] are most the likely source for the deviations from the ideal octahedral geometries. The distortions are best seen in the twists of the triangular faces, that is, 40.27(7) and 46.43(5)° for the gallium and indium structures, respectively, compared to the ideal octahedral angle of 60°. Enantiomeric pairs associate in their respective crystal lattices via S- -S contacts of 3.598(4) and 3.592(2) A, respectively. [Pg.254]

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Geometry structures

Octahedral geometry

Xanthates

Xanthation

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