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Octahedral environment, bonding

The network comprises W(IV) ions, which are connected to nearest neighbour Fe(II) ions through cyanide bridges in a three-dimensional grid-like arrangement. The Fe(II) ions are in an octahedral environment, bonded to four nearest neighbour W(IV) ions two axial water molecules complete the sixfold coordination. [Pg.300]

Figure 4.2. Simplified schematic orbital and state diagrams for a rf metal in an octahedral environment showing d and n bonding and rr andbonding (n ) orbitals. A strong crystal field is assumed so that the t2 levels are filled. Ligand to metal charge transfer states are ignored. Figure 4.2. Simplified schematic orbital and state diagrams for a rf metal in an octahedral environment showing d and n bonding and rr andbonding (n ) orbitals. A strong crystal field is assumed so that the t2 levels are filled. Ligand to metal charge transfer states are ignored.
The halogenation reactions of the monomeric products has not been reported, but oxidation occurs on treatment of Fe(CO)3(vp) and Ru(CO)3 vp with HCl or HBr to give M(Il)-carbon bonded species, the halogen becoming attached to the metal in an octahedral environment. The ring-size was not reported. [Pg.29]

SrLaCu04 has been prepared (102) under high-pressure oxygen and the product has been found to contain the Cu3+ ion in a distorted octahedral environment, the Cu-O bond distances in the compound are 4 1.88 and 2 2.23 A. [Pg.55]


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See also in sourсe #XX -- [ Pg.20 ]




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Bonding octahedral

Octahedral environment

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