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O Driscoll

The success of the multifunctional initiators in the preparation of block and graft copolymers depends critically on the kinetics and mechanism of radical production. In particular, the initiator efficiency, the susceptibility to and mechanism of transfer to initiator, and the relative stability of the various radical generating functions. Each of these factors has a substantial influence on the nature and homogeneity of the polymer formed. Features of the kinetics of polymerizations initiated by multifunctional initiators have been modeled by O Driscoll and Bevington 64 and Choi and Lei.265... [Pg.386]


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See also in sourсe #XX -- [ Pg.273 ]

See also in sourсe #XX -- [ Pg.19 ]




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Driscoll

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