Nucleophilicity, of metal carbonyl anions

Nucleophilicity, of metal carbonyl anions, 25 3 Nucleophilic substimtion reactions, in high-nuclearity carbonyl clusters, 30 187-202... 

The success of these reactions depends on the nucleophihc-ity of the anions used. Numerous accounts have discussed the basicity and the nucleophilicity of metal carbonyl anions and their influence on reactivity. Electrochemical studies (see Section 9.3) are particularly helpful in predicting the feasibility of reactions. The driving force for these reactions is often attributed to the precipitation of the insoluble salt. In spite of this, the free energies of reaction can be close to zero. In some cases, the metal-metal bond is cleaved by salts or an... 

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See also in sourсe #XX -- [ ]

See also in sourсe #XX -- [ ]

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