Trigonal planar center nucleophilic substitution

The most common example of electrophilic substitution at a trigonal planar center is electrophilic aromatic substitution, which will serve as our archetype. Aromaticity was covered in Section 1.9, and the reactivity trends of aromatics will be covered in detail in Chapter 5. Chapter 8 has additional reaction examples. Aromatic rings are usually poor nucleophiles therefore excellent electrophiles are needed for the reaction to proceed. 

This is the almost exclusive route in basic media for replacement of a leaving group hound to a donble bond. This reaction was introduced in Section 4.5, Nucleophilic Substitution at a Trigonal Planar Center. The most common substrates for this reaction are the carboxyl derivatives. A nucleophile adds first via path Adileaving group departs via the beta elimination from an anion path Ep. 

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