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Nucleophilic reactions Baylis-Hillman carbonates, asymmetric

Baylis-Hillman carbonate is a good substrate for asymmetric allylic substitution reaction, and various nucleophiles have been involved in this transformation. As shown in Scheme 9.36, the intermediate 72 (mechanistically formed by Michael... [Pg.335]

Morita-Baylis-Hillman carbonates undergo an hydrolysis in the presence of the asymmetric organocatalyst, hydroquinidine[anthraquinone-l,4-diyl] diether, and Cap2 in aqueous iV,iV-dimethylacetamide, yielding the allylic alcohol Tracer studies using showed that water is the nucleophile in the hydrolysis reaction. It is... [Pg.310]

See other pages where Nucleophilic reactions Baylis-Hillman carbonates, asymmetric is mentioned: [Pg.52]    [Pg.439]    [Pg.48]    [Pg.79]    [Pg.412]    [Pg.331]    [Pg.372]    [Pg.112]    [Pg.794]    [Pg.334]    [Pg.794]   


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Asymmetric Baylis-Hillman

Asymmetric Baylis-Hillman reaction

Asymmetric carbon

Baylis asymmetric

Baylis-Hillman

Baylis-Hillman reaction

Baylis-Hillman reaction asymmetric carbonate

Carbon nucleophile

Carbon nucleophiles

Carbonates, asymmetric Baylis-Hillman

Hillman

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