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Nucleophilic aliphatic isotope effects

In TFE the secondary isotope effect for solvolysis ( h/ d3)s is found to have the value 1.46 and that for Na,Np-rearrangement (kH/kD3)r has the value 1.42 (Szele and Zollinger, 1981). The two isotope effects are similar to the largest values observed in nucleophilic aliphatic substitutions following the DN + AN mechanism (Shiner,... [Pg.174]

See other pages where Nucleophilic aliphatic isotope effects is mentioned: [Pg.423]    [Pg.431]    [Pg.1020]    [Pg.18]    [Pg.937]    [Pg.482]    [Pg.131]    [Pg.139]   
See also in sourсe #XX -- [ Pg.334 , Pg.335 ]

See also in sourсe #XX -- [ Pg.311 , Pg.312 ]

See also in sourсe #XX -- [ Pg.334 , Pg.335 ]



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