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Nucleophile deuterium KIEs

The newest type of KIE that has been used to characterize the transition state of the Menshutkin reaction is a secondary incoming nucleophile deuterium KIE. These KIEs are measured by using primary amines labelled with deuterium at the nitrogen of the nucleophile [reaction (25)]. [Pg.183]

In fact, Lee and collaborators (Lee et al., 1991) measured both the secondary a-deuterium and the secondary incoming nucleophile deuterium KIEs for four different Menshutkin reactions (Table 22). The secondary... [Pg.183]

See other pages where Nucleophile deuterium KIEs is mentioned: [Pg.184]    [Pg.185]    [Pg.185]    [Pg.184]    [Pg.185]    [Pg.185]    [Pg.399]   
See also in sourсe #XX -- [ Pg.320 ]



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Deuterium KIEs

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