Nuclear motion, the principle of least, and

Nuclear motion, the principle of least, and the theory of stereoelectronic control, 24, 113 Nucleophiles, partitioning of carbocations between addition and deprotonation. 35, 67 Nucleophilic aromatic photosubstitution, 11,225 Nucleophilic catalysis of ester hydrolysis and related reactions, 5,237 Nucleophilic displacement reactions, gas-phase, 21, 197... 

Nuclear motion, the principle of least, and the theory of stereoelectronic control, 24, 113... 

Stability and reactivity of crown-ether complexes, 17, 279 Stereochemistry, static and dynamic, of alkyl and analogous groups, 25, 1 Stereoelectronic control, the principle of least nuclear motion and the theory of, 24, 113 Stereoselection in elementary steps of organic reactions, 6, 185 Steric isotope effects, experiments on the nature of, 10, 1... 

The Principle of Least Nuclear Motion and the Theory of Stereoelectric Control... 

The frontier orbital explanation of the anomeric effect successes and failures 148 Calculations on tetrahedral intermediates 152 ALPH and the principle of least nuclear motion 154... 

In the third section, ALPH will be recast in terms of the principle of least nuclear motion, PLNM, which does not apply to reactions with late transition states. It will then be shown how for heterolytic reactions at saturated carbon, PLNM and ALPH make the same predictions. Key reactions of various compound types, which have been taken as evidence for ALPH, will be shown to be also predicted by PLNM. 

ALPH AND THE PRINCIPLE OF LEAST NUCLEAR MOTION (PLNM)... 

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