Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Normalization of Daughter States

The commutation relations (42) can be used to normalize the A-electron states obtained by acting on (A — 2)-electron states with Kramers pair creation operators [8], Suppose that P) is a properly normalized (N — 2)-electron state which is annihilated by By, i.e., suppose that [Pg.192]

We would like to choose the normalizing constant a in such a way that the A-electron state [Pg.192]

In other words, A is the number of electrons in the subshell y in the parent state IP). This need not be zero, even though By annihilates IP). More generally, one can show [Pg.193]

This last relationship can be used to normalize the states obtained by creating successively larger numbers of Kramers pairs in a subshell until no more states with the symmetry and seniority of the parent state can be created by further filling of the sub shell. [Pg.193]


See other pages where Normalization of Daughter States is mentioned: [Pg.185]    [Pg.192]   


SEARCH



Daughter state normalization

Normal state, 154

© 2024 chempedia.info