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Normal micelles in non-aqueous media

Micellization of both ionic and non-ionic surfactants occurs in solvents such as [Pg.490]

2-diols, triols, and formamide which have sufficient hydrogen bonding centers that [Pg.490]

Carbocation or oxonium ion derived micelles form in concentrated sulfuric acid, a medium which is unsuitable for most organic solutes [20], They are generated by dissolving the ether or alkene in sulfuric acid  [Pg.491]

The effects of a variety of added organic solvents upon the thermodynamics of micellization have been investigated by lonescu and Fung [129], [Pg.491]

Aggregation of surfactants in apolar solvents, e.g., aliphatic or aromatic hydrocarbons, occurs provided that small amounts of water are present [1,126,127], These aggregates are often called reverse micelles, although the solutions do not always appear to have a critical micelle concentration, and surfactant association is often governed by a multiple equilibrium, mass action, model vith a large spread of aggregate sizes [130,131], It has recently been suggested that the existence of a monomer f -mer equilibrium should be used as a criterion of micellization, and that this term should not be applied to self-associated systems which involve multiple equilibria [132], [Pg.491]


See other pages where Normal micelles in non-aqueous media is mentioned: [Pg.490]    [Pg.490]   


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In micelles

Micelle normal

Micelles media

Micellization in non-aqueous media

Non-aqueous

Non-aqueous media

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