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Nonunimolecular Elcb Eliminations Energy Profile and Rate Law

2 Nonunimolecular Elcb Eliminations Energy Profile and Rate Law [Pg.190]

The enolate concentration follows from the equilibrium condition [enolate] = K [aldol] [NaOEt] [Pg.191]

Inserting Eq. 4.24 into Eq. 4.23 yields d [alkene] = k jaldol] [Na0Et] [Pg.191]

this elimination takes place bimolecularly. Therefore, the designation Elcb for this mechanism is justified only if one thinks of the unimolecularity of the rate-determining step. [Pg.191]

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And ElcB elimination

And rate law

ElcB elimination

Energy profil

Energy profile

Energy profile and rate law

Rate profile

Rates and Rate Laws